CA River Plate 
| 2006-01-26 | Copa Libertadores Qualifying | CD Oriente Petrolero | (H) | 6 | - 0 | W | |
| 2006-02-02 | Copa Libertadores Qualifying | CD Oriente Petrolero | (A) | 2 | - 0 | W | |
| 2006-02-16 | Copa Libertadores Group stage Group 8 | Club Libertad | (A) | 0 | - 2 | L | |
| 2006-03-08 | Copa Libertadores Group stage Group 8 | CD El Nacional | (H) | 4 | - 3 | W | |
| 2006-03-16 | Copa Libertadores Group stage Group 8 | Paulista FC | (H) | 4 | - 1 | W | |
| 2006-04-05 | Copa Libertadores Group stage Group 8 | Paulista FC | (A) | 1 | - 2 | L | |
| 2006-04-12 | Copa Libertadores Group stage Group 8 | CD El Nacional | (A) | 0 | - 2 | L | |
| 2006-04-20 | Copa Libertadores Group stage Group 8 | Club Libertad | (H) | 1 | - 0 | W | |
| 2006-04-26 | Copa Libertadores Round of 16 | SC Corinthians | (H) | 3 | - 2 | W | |
| 2006-05-04 | Copa Libertadores Round of 16 | SC Corinthians | (A) | 3 | - 1 | W | |
| 2006-05-11 | Copa Libertadores Quarter finals | Club Libertad | (H) | 2 | - 2 | D | |
| 2006-07-18 | Copa Libertadores Quarter finals | Club Libertad | (A) | 1 | - 3 | L |