| 31.10.07 20:00 | Villarreal CF |  |
 |
Levante UD | -:- |
| UD Almeria |  |
 |
Real Zaragoza | -:- | |
| Betis Sevilla |  |
 |
CA Osasuna | -:- | |
| Getafe CF |  |
 |
Athletic Bilbao | -:- | |
| Recreativo Huelva |  |
 |
Racing Santander | -:- | |
| RCD Español |  |
 |
Real Murcia | -:- | |
| Deportivo de Coruña |  |
 |
RCD Mallorca | -:- | |
| 31.10.07 21:00 | Valencia CF |  |
 |
Real Madrid | -:- |
| 31.10.07 22:00 | Atlético Madrid |  |
 |
Sevilla FC | -:- |
| 01.11.07 22:00 | Real Valladolid |  |
 |
FC Barcelona | -:- |